The effectiveness of classroom instruction is an focus and hot topics in instruction Research. Based on the systematic and procedural analysis of classroom instruction, classroom instruction is a dynamic structure system, which contains the vector system, the conceptive system, the positioning system, the condition system, the organization system and the output system. Considering the structure of the system of classroom instruction, the effectiveness of classroom instruction characterized as such five dimensions, effectiveness, efficiency, effectiveness, efficiency and effect. Focus on the effectiveness of the characterization, the effectiveness of classroom instruction explicit to 'five degree' standards, the reliability, the internal validity, the external validity, the difficulty and the discrimination. From the effectiveness of the standards, the effectiveness of classroom instruction is the organic coupling of instruction realm, instruction process and instruction states.